Reconsidering Water Electrolysis: Producing Hydrogen at Cathodes Together with Selective Oxidation of n-Butylamine at Anodes,ChemSusChem

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Reconsidering Water Electrolysis: Producing Hydrogen at Cathodes Together with Selective Oxidation of n-Butylamine at Anodes
ChemSusChem ( IF 7.5 ) Pub Date : 2017-11-22 03:56:31 , DOI: 10.1002/cssc.201701802
Song Xue ₁ , Sebastian Watzele ₁ , Viktor Čolić _{1,

2} , Kurt Brandl ₁ , Batyr Garlyyev ₁ , Aliaksandr S. Bandarenka _{1,

3,

4}

Affiliation

Twice the value: In electrocatalytic water splitting devices, decreasing anodic overpotential and simultaneously changing the anodic reaction to produce valuable chemicals instead of O₂ would be a major improvement in overall cost efficiency. Oxyhydroxides of cobalt, nickel/iron, and nickel are industrially relevant electrocatalysts that, as anodes, can selectively catalyze the production of n-butyronitrile from n-butylamine as an easily retrievable valuable product.

中文翻译：

重新考虑水电解：在阴极处产生氢气，并在阳极处选择性氧化正丁胺

价值的两倍：在电催化水分解装置中，减少阳极过电势并同时改变阳极反应以生产有价值的化学物质（而不是O _2）将是总体成本效率的重大提高。钴，镍/铁和镍的羟基氧化物是与工业相关的电催化剂，作为阳极，可以选择性地催化正丁胺作为可轻松回收的有价值产品生产正丁腈。

更新日期：2017-11-22

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