A solution-processable dissymmetric porous organic cage†,Molecular Systems Design & Engineering

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A solution-processable dissymmetric porous organic cage†
Molecular Systems Design & Engineering ( IF 3.6 ) Pub Date : 2017-11-22 00:00:00 , DOI: 10.1039/c7me00090a
A. G. Slater _{1,

2,

3,

4} , M. A. Little _{1,

2,

3,

4} , M. E. Briggs _{1,

2,

3,

4} , K. E. Jelfs _{4,

5,

6,

7} , A. I. Cooper _{1,

2,

3,

4}

Affiliation

Two dissymmetric racemic analogues of the chiral porous organic cage, CC3, were isolated and unambiguously characterised as a racemate pair of the R,R,R,S,S,S and S,S,S,R,R,R-diastereomers (CC3-RS and CC3-SR). CC3-RS/CC3-SR equals the highest porosity measured for CC3 but is an order of magnitude more soluble, making it an excellent candidate for incorporation into a membrane for separation applications.

中文翻译：

可溶液处理的不对称多孔有机笼†

分离了手性多孔有机笼的两个不对称外消旋类似物CC3，并明确地将其表征为R，R，R，S，S，S和S，S，S，R，R，R，非对映异构体的外消旋物对（CC3 - RS和CC3 - SR）。CC3 - RS / CC3 - SR等于CC3测得的最高孔隙率但溶解度高一个数量级，使其成为掺入用于分离应用的膜的极佳候选者。

更新日期：2017-11-22

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