Crystal Growth with Macromolecular Additives,Chemical Reviews

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Crystal Growth with Macromolecular Additives
Chemical Reviews ( IF 51.4 ) Pub Date : 2017-11-22 00:00:00 , DOI: 10.1021/acs.chemrev.7b00285
Alexander G. Shtukenberg ₁ , Michael D. Ward ₁ , Bart Kahr ₁

Affiliation

Interactions of macromolecules with growing crystalline surfaces play an important role in biomineralization, determine survival of some organisms at low temperatures, and offer a range of potential industrial applications. The current understanding of crystal growth processes in the presence of macromolecules, including peptides and proteins, is reviewed, with a focus on interactions between macromolecules and surfaces of crystalline materials, macromolecule adsorption on different types of crystal surfaces, crystallization kinetics in the presence of macromolecular additives, macromolecule incorporation, and defect generation. Throughout, special attention is paid to the selectivity of macromolecule adsorption on, and incorporation within, crystal surfaces. The special role played by the size and complexity of macromolecules as compared to other crystallization additives is emphasized.

中文翻译：

高分子添加剂的晶体生长

大分子与增长的晶体表面的相互作用在生物矿化中起着重要作用，决定了某些生物在低温下的存活，并提供了一系列潜在的工业应用。综述了目前对包括肽和蛋白质在内的大分子存在下晶体生长过程的理解，重点是大分子与晶体材料表面之间的相互作用，大分子在不同类型晶体表面上的吸附，大分子存在下的结晶动力学添加剂，大分子掺入和缺陷产生。贯穿整个过程，要特别注意大分子在晶体表面上的吸附以及在晶体表面掺入的选择性。

更新日期：2017-11-22

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