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Facile synthesis of hollow MnFe2O4 nanoboxes based on galvanic replacement reaction for fast and sensitive VOCs sensor
Sensors and Actuators B: Chemical ( IF 8.0 ) Pub Date : 2017-11-21 , DOI: 10.1016/j.snb.2017.11.067
Lu Zhang , Gang Wang , Feng Yu , Yang Zhang , Bang-Ce Ye , Yingchun Li

Hollow MnFe2O4 nanoparticles were successfully synthesized based on simple galvanic replacement reaction with Mn3O4 as a precursor. The chemical composition and nanostructure of the as-prepared samples were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy. MnFe2O4 was applied to decorate interdigital electrodes and the obtained sensors were used to detect fourteen kinds of volatile organic compounds at different operation temperature from 160 °C to 280 °C.

Results show that the sensor has good sensitivity, repeatability and long-term stability for ethanol gas determination at 210 °C. The detection linear range for ethanol is 2 ∼ 400 ppm, and the response and the recovery time was 7.5 s and 8.0 s, respectively. Besides, the fabricated sensor also displayed decent performance in measuring n-decane in the concentration range of 2 ∼ 400 ppm at 260 °C. Finally, gas-sensing mechanism of the prepared sensor was clearly studied.



中文翻译:

基于电流置换反应的空心MnFe 2 O 4纳米盒的快速合成,用于快速灵敏的VOCs传感器

基于简单的电流置换反应,以Mn 3 O 4为前体,成功合成了空心MnFe 2 O 4纳米颗粒。通过扫描电子显微镜,透射电子显微镜,X射线衍射和X射线光电子能谱表征所制备样品的化学组成和纳米结构。MnFe 2 O 4用于装饰叉指电极,所获得的传感器用于在160℃至280℃的不同工作温度下检测14种挥发性有机化合物。

结果表明,该传感器对于210°C的乙醇气体测定具有良好的灵敏度,可重复性和长期稳定性。乙醇的检测线性范围为2〜400 ppm,响应和恢复时间分别为7.5 s和8.0 s。除此之外,在260°C的2〜400 ppm浓度范围内,所制造的传感器在癸烷的测量中也显示出不错的性能。最后,对所制备传感器的气敏机理进行了清晰的研究。

更新日期:2017-11-21
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