Iminium and enamine catalysis in enantioselective photochemical reactions,Chemical Society Reviews

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Iminium and enamine catalysis in enantioselective photochemical reactions
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2017-11-20 00:00:00 , DOI: 10.1039/c7cs00509a
You-Quan Zou _{1,

2,

3,

4} , Fabian M. Hörmann _{1,

2,

3,

4} , Thorsten Bach _{1,

2,

3,

4}

Affiliation

Although enantioselective catalysis under thermal conditions has been well established over the last few decades, the enantioselective catalysis of photochemical reactions is still a challenging task resulting from the complex enantiotopic face differentiation in the photoexcited state. Recently, remarkable achievements have been reported by a synergistic combination of organocatalysis and photocatalysis, which have led to the expedient construction of a diverse range of enantioenriched molecules which are generally not easily accessible under thermal conditions. In this tutorial review, we summarize and highlight the most significant advances in iminium and enamine catalysis of enantioselective photochemical reactions, with an emphasis on catalytic modes and reaction types.

中文翻译：

对映选择性光化学反应中的亚胺和烯胺催化

尽管在过去的几十年中已经很好地确立了在热条件下的对映选择性催化，但是光化学反应的对映选择性催化仍然是具有挑战性的任务，这是由于在光激发态下复杂的对映体表面分化所致。近来，已经报道了有机催化和光催化的协同结合所取得的显著成就，这导致了便利地构建了多种对映体富集的分子，这些分子通常在热条件下不易获得。在本教程的复习中，我们总结并突出了对映选择性光化学反应在亚胺和烯胺催化中的最重要进展，重点是催化方式和反应类型。

更新日期：2017-11-20

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