Alkyl radical triggered in situ SO2-capture cascades,Chemical Communications

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Alkyl radical triggered in situ SO2-capture cascades
Chemical Communications ( IF 4.9 ) Pub Date : 2017-11-21 00:00:00 , DOI: 10.1039/c7cc08362a
Xiaolong Su _{1,

2,

3} , Honggui Huang _{1,

2,

3} , Wei Hong _{1,

2,

3} , Jianchao Cui _{1,

2,

3} , Menglin Yu _{1,

2,

3} , Yi Li _{1,

2,

3}

Affiliation

An unprecedented in situ SO₂-capture cascade triggered by alkyl radicals has been documented herein. Mechanistic investigations suggest that, triggered by alkyl radicals, SO₂ was released in situ and subsequently fixed into polycyclic small molecules. A wide range of alkylsulfonyl substituted polycyclic compounds were easily prepared with high yields and good functional group tolerability.

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