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Direct alkylheteroarylation of alkenes via photoredox mediated C–H functionalization
Chemical Communications ( IF 4.3 ) Pub Date : 2017-11-20 00:00:00 , DOI: 10.1039/c7cc06484e
Lijun Gu 1, 2, 3, 4, 5 , Ying Gao 5, 6, 7 , Xianhong Ai 1, 2, 3, 4, 5 , Cheng Jin 5, 8, 9 , Yonghui He 1, 2, 3, 4, 5 , Ganpeng Li 1, 2, 3, 4, 5 , Minglong Yuan 3, 4, 5, 10
Affiliation  

The direct alkylheteroarylation of alkenes with cyclic and acyclic ethers via distal heteroaryl ipso-migration has been accomplished through the design of a photoredox-mediated C–H functionalization pathway. The use of inexpensive ethers as radical precursors combined with a straightforward method makes this a practical approach.

中文翻译:

通过光氧化还原介导的C–H官能团直接进行烯烃的烷基杂芳基化

与烯烃的直接alkylheteroarylation环状和无环醚经由远端杂本位-migration已经通过photoredox介导的C-H官能化途径的设计来实现。使用廉价的醚作为自由基前体,再加上简单的方法,使之成为一种实用的方法。
更新日期:2017-12-01
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