Metal‐Free, Visible‐Light‐Mediated Direct C−H Trifluoromethylation of Hydrazones with NADH Coenzyme Model Catalyst,Asian Journal of Organic Chemistry

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Metal‐Free, Visible‐Light‐Mediated Direct C−H Trifluoromethylation of Hydrazones with NADH Coenzyme Model Catalyst
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2017-11-29 , DOI: 10.1002/ajoc.201700570
Bei Huang ₁ , Xiao-Song Bu ₂ , Jun Xu ₁ , Jian-Jun Dai ₁ , Yi-Si Feng ₂ , Hua-Jian Xu _{1,

2}

Affiliation

A metal‐free, visible‐light‐mediated direct C−H bond trifluoromethylation of N,N‐dialkylhydrazones with an NADH coenzyme model catalyst has been developed. The use of NADH coenzyme model makes this reaction more meaningful. Advantages of this reaction include avoidance of transition metal catalysts, high levels of functional group tolerance, and mild reaction conditions. This reaction represents a method to synthesize substituted hydrazones.

中文翻译：

带有NADH辅酶模型催化剂的Hy的无金属，可见光介导的直接CH三氟甲基化

已经开发出了一种无金属，可见光介导的N，N-二烷基azo唑烷与NADH辅酶模型催化剂直接进行C氢键三氟甲基化反应。NADH辅酶模型的使用使该反应更有意义。该反应的优点包括避免过渡金属催化剂，高水平的官能团耐受性和温和的反应条件。该反应代表合成取代的的方法。

更新日期：2017-11-29

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