Salen-type ligands have been used extensively to stabilize metals for homogeneous catalysis. It has been demonstrated that the marriage of complexes of salen with porous materials is a promising way to combine the attractive properties of the salen complexes with those of the porous structures. In this review, we summarize the recent research progress in metallosalen-based crystalline porous materials (CPMs), including metal–organic frameworks, coordination metallacycles, and covalent organic frameworks. Emphasis is placed on the syntheses, and structures of these porous materials, and their properties of catalysis, molecule separation, sensing and magnetic resonance imaging.

Salen型配体已广泛用于稳定金属以进行均相催化。已经证明，塞伦络合物与多孔材料的结合是将塞伦络合物的吸引人的特性与多孔结构的诱人特性相结合的有前途的方式。在这篇综述中，我们总结了基于金属硅铝的晶体多孔材料（CPM）的最新研究进展，包括金属-有机骨架，配位金属环和共价有机骨架。重点放在这些多孔材料的合成，结构，催化，分子分离，传感和磁共振成像的特性上。