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Adsorption-Induced Structural Phase Transformation in Nanopores
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2017-11-20 05:40:32 , DOI: 10.1002/anie.201708993
Bogdan Kuchta 1 , Ege Dundar 2 , Filip Formalik 3 , Philip L. Llewellyn 1 , Lucyna Firlej 4
Affiliation  

Between solid and liquid: New type of structural transformation has been observed in a model of methane molecules adsorbed in micropores of the IRMOF-1 metal–organic framework (MOF). The mechanism of the transformation is defined by a probability distribution function. The methane structure in the pore is characterized by limited mobility, and represents a new state of matter, intermediate between solid and liquid.

中文翻译:

吸附诱导的纳米孔结构相变

在固体和液体之间:在吸附于IRMOF-1金属-有机骨架(MOF)的微孔中的甲烷分子模型中,观察到了新型的结构转变。转换的机制由概率分布函数定义。孔中的甲烷结构以有限的迁移率为特征,代表了介于固体和液体之间的一种新的物质状态。
更新日期:2017-11-20
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