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Metal-Free Aerobic Oxidative Cyanation of Tertiary Amines: Azobis(isobutyronitrile) (AIBN) as a Sole Cyanide Source
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2017-11-17 00:00:00 , DOI: 10.1021/acs.joc.7b02021
Peng-Yu Liu 1 , Chao Zhang 1 , Shi-Chen Zhao 1 , Fang Yu 1 , Fei Li 1 , Yu-Peng He 1
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An aerobic oxidative cyanation for the synthesis of α-aminonitriles was reported. The formation of C(sp3)-CN bonds was achieved under a metal-free condition by utilizing azobis(isobutyronitrile) as a sole organic cyanide source with the combination of pivalic acid and sodium acetate as additives.

中文翻译:

叔胺的无金属好氧氧化氰化:偶氮二异丁腈(AIBN)作为唯一氰化物源

据报道,有氧氧化氰化反应可合成α-氨基腈。C(sp 3)-CN键的形成是在无金属条件下通过使用偶氮二(异丁腈)作为唯一的有机氰化物源,新戊酸和乙酸钠的组合作为添加剂而实现的。
更新日期:2017-11-19
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