Metal-Free Aerobic Oxidative Cyanation of Tertiary Amines: Azobis(isobutyronitrile) (AIBN) as a Sole Cyanide Source,The Journal of Organic Chemistry

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Metal-Free Aerobic Oxidative Cyanation of Tertiary Amines: Azobis(isobutyronitrile) (AIBN) as a Sole Cyanide Source
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2017-11-17 00:00:00 , DOI: 10.1021/acs.joc.7b02021
Peng-Yu Liu ₁ , Chao Zhang ₁ , Shi-Chen Zhao ₁ , Fang Yu ₁ , Fei Li ₁ , Yu-Peng He ₁

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An aerobic oxidative cyanation for the synthesis of α-aminonitriles was reported. The formation of C(sp³)-CN bonds was achieved under a metal-free condition by utilizing azobis(isobutyronitrile) as a sole organic cyanide source with the combination of pivalic acid and sodium acetate as additives.

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