Transition-Metal-Free C–S Bond Formation: Synthesis of Polysubstituted Diaryl Sulfides and α-Thioarylcarbonyl Compounds,The Journal of Organic Chemistry

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Transition-Metal-Free C–S Bond Formation: Synthesis of Polysubstituted Diaryl Sulfides and α-Thioarylcarbonyl Compounds
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2017-11-17 00:00:00 , DOI: 10.1021/acs.joc.7b02384
Liang-Hua Zou _{1,

2} , Cong Zhao _{1,

2} , Ping-Gui Li ₃ , Ying Wang ₁ , Jie Li ₁

Affiliation

A transition-metal-free protocol for the construction of C–S bonds has been developed. Acetylacetone acts as a new and green aryl source for the synthesis of polysubstituted diarylsulfides bearing a free hydroxy group and a ketone group, which provides a new access to a series of flavonoids containing a thioaryl group. In addition, a series of α-thioarylcarbonyl compounds are obtained in good to excellent yields.

中文翻译：

无过渡金属的C–S键形成：多取代的二芳基硫醚和α-硫代芳基羰基化合物的合成

已经开发出用于构建C–S键的无过渡金属的方案。乙酰丙酮是合成带有游离羟基和酮基的多取代二芳基硫醚的一种新的绿色芳基来源，它为一系列含有硫代芳基的类黄酮提供了新途径。另外，以良好至优异的产率获得了一系列α-硫代芳基羰基化合物。

更新日期：2017-11-19

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