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SnO2 (n)-NiO (p) composite nanowebs: Gas sensing properties and sensing mechanisms
Sensors and Actuators B: Chemical ( IF 8.0 ) Pub Date : 2017-11-15 , DOI: 10.1016/j.snb.2017.11.063
Jae-Hun Kim , Jae-Hyoung Lee , Ali Mirzaei , Hyoun Woo Kim , Sang Sub Kim

Aiming to optimize SnO2-NiO nanocomposite sensors for detection of hazardous gases, a series of xSnO2-(1-x) NiO composite nanowebs with different compositions (x = 0.1, 0.3, 0.5, 0.7, and 0.9) were synthesized using an electrospinning process. The formation of long and continuous SnO2-NiO nanowebs was verified. Depending on the composition, xSnO2-(1-x) NiO composite nanowebs‎ showed either n-type (SnO2-rich composition) or p-type (NiO-rich composition) gas-sensing behavior. The best sensing performance was obtained for the nanowebs of 0.5SnO2-0.5NiO. The presence of plenty of p-n heterojunctions along with the high oxygen adsorption property of NiO were the main reasons for the high response to the NO2 and C6H6 gases at this optimized composition.



中文翻译:

SnO 2n)-NiO(p)复合纳米纤维网:气敏特性和传感机理

为了优化用于检测有害气体的SnO 2 -NiO纳米复合传感器,使用以下方法合成了一系列具有不同成分(x = 0.1、0.3、0.5、0.7和0.9)的xSnO 2-(1-x)NiO复合纳米网。静电纺丝过程。验证了长而连续的SnO 2 -NiO纳米纤维网的形成。取决于组成,xSnO 2-(1-x)NiO复合纳米纤维网表现出n型(富SnO 2的组成)或p型(富NiO的组成)气敏行为。对于0.5SnO 2 -0.5NiO的纳米纤维网,获得了最佳的感测性能。存在大量p - n异质结以及NiO的高氧吸附性能是在这种优化组成下对NO 2和C 6 H 6气体产生高响应的主要原因。

更新日期:2017-11-15
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