There is tremendous interest in graphene since its discovery. In the past few years, graphene-based materials attracted much attention in analytical chemistry due to their large surface area, π-electron-rich structure and good thermal and chemical stability. In this article, an overview of the most significant results so far achieved in the application of graphene-based materials: graphene, graphene oxide and graphene quantum dot as chromatographic stationary phases is presented. In particular, we focus on the separation performance in capillary gas chromatography, in high performance liquid chromatography and capillary electrochromatography. Different synthesis strategies (physical coating, chemical bonding and some other preparation techniques) in preparing graphene-based stationary phases and the relationship with chromatographic behaviour is also considered. Finally, we discuss possible challenges and future perspectives in this rapidly developing field.

自从发现石墨烯以来，人们对其产生了极大的兴趣。在过去的几年中，石墨烯基材料因其较大的表面积，富π电子的结构以及良好的热化学稳定性而在分析化学中引起了广泛的关注。本文概述了迄今为止在基于石墨烯的材料的应用中获得的最重要的结果：作为色谱固定相的石墨烯，氧化石墨烯和石墨烯量子点。特别是，我们专注于毛细管气相色谱法，高效液相色谱法和毛细管电色谱法中的分离性能。不同的合成策略（物理涂层，化学键合和其他一些制备技术）在石墨烯基固定相的制备中以及与色谱行为之间的关系。最后，我们讨论了这个快速发展领域中可能存在的挑战和未来前景。