当前位置:
X-MOL 学术
›
Adv. Synth. Catal.
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
One Pot Synthesis of γ-Benzopyranones via Iron-Catalyzed Aerobic Oxidation and Subsequent 4-Dimethylaminopyridine Catalyzed 6-endo Cyclization
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2017-11-17 03:01:49 , DOI: 10.1002/adsc.201700993 Di Zhai 1 , Lingzhu Chen 2 , Minqiang Jia 1 , Shengming Ma 1, 2, 3
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2017-11-17 03:01:49 , DOI: 10.1002/adsc.201700993 Di Zhai 1 , Lingzhu Chen 2 , Minqiang Jia 1 , Shengming Ma 1, 2, 3
Affiliation
One-pot synthesis of γ-benzopyranones was realized in decent yields and excellent regioselectivities via iron-catalyzed aerobic oxidation and 4-dimethylaminopyridine-catalyzed cyclization of related propargylic alcohols. Derivatizations to aromatic substituted γ-benzopyranones and synthesis of naturally occurring 3′,4′-dimethoxyflavone have also been realized.
中文翻译:
铁催化好氧氧化反应及随后的4-二甲基氨基吡啶催化6-内酯环化反应一锅合成γ-苯并吡喃酮
通过铁催化的好氧氧化和4-二甲基氨基吡啶催化的相关炔丙醇的环化反应,可以实现一锅合成γ-苯并吡喃酮的高产和极好的区域选择性。还已经实现了芳族取代的γ-苯并吡喃酮的衍生化和天然存在的3',4'-二甲氧基黄酮的合成。
更新日期:2017-11-17
中文翻译:
铁催化好氧氧化反应及随后的4-二甲基氨基吡啶催化6-内酯环化反应一锅合成γ-苯并吡喃酮
通过铁催化的好氧氧化和4-二甲基氨基吡啶催化的相关炔丙醇的环化反应,可以实现一锅合成γ-苯并吡喃酮的高产和极好的区域选择性。还已经实现了芳族取代的γ-苯并吡喃酮的衍生化和天然存在的3',4'-二甲氧基黄酮的合成。