Ring-Size-Modulated Reactivity of Putative Dicobalt-Bridging Nitrides: C−H Activation versus Phosphinimide Formation,Angewandte Chemie International Edition

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Ring-Size-Modulated Reactivity of Putative Dicobalt-Bridging Nitrides: C−H Activation versus Phosphinimide Formation
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-11-17 05:20:59 , DOI: 10.1002/anie.201708966
Peng Cui ₁ , Qiuran Wang ₁ , Samuel P. McCollom ₁ , Brian C. Manor ₁ , Patrick J. Carroll ₁ , Neil C. Tomson ₁

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The products of C−H amination, hydrogen-atom transfer, and phosphinimide formation were obtained following the thermal activation of dicobalt-bridging azides bound by flexible macrocyclic ligands. The size of the macrocycle was found to influence the product distribution.

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