Pot-Economical Synthesis of Hydroxylated Arylethenyl-arylethynyl-arenes through Sequential Decarboxylative Perkin–Sonogashira Reactions,Asian Journal of Organic Chemistry

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Pot-Economical Synthesis of Hydroxylated Arylethenyl-arylethynyl-arenes through Sequential Decarboxylative Perkin–Sonogashira Reactions
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2017-11-17 05:26:12 , DOI: 10.1002/ajoc.201700504
Amit Shard _{1,

2} , Rajesh Kumar _{1,

2} , Danish Equbal ₃ , Arun Kumar Sinha _{1,

2,

3}

Affiliation

Harmonious tandem: A skeletally diverse chemical library of hydroxy-substituted arylethenyl-arylethynyl-arenes [C(sp²)−C(sp²) and C(sp²)−C(sp) framework] was prepared in good yields from terminal-alkyne-elaborated halogen-functionalized hydroxylated stilbenes. Their topological connectivity might afford them exceptional optoelectronic and medicinal properties. The products are amenable to downstream modification and can be further utilized for the synthesis of versatile molecular frameworks.

中文翻译：

通过顺序脱羧珀金-Sonogashira反应锅经济合成羟基化的芳基乙烯基-芳基乙炔基芳烃

和谐串联：从端基-上以良好的收率制备了羟基取代的芳基乙烯基-芳基乙炔基芳烃[C（sp ²）-C（sp ²）和C（sp ²）-C（sp）骨架]的骨架形式多样的化学库。炔烃修饰的卤素官能化羟基丁苯醚。它们的拓扑连接性可能会为它们提供出色的光电和医学特性。该产物适于下游修饰，并且可以进一步用于合成通用分子框架。

更新日期：2017-11-17

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