Diastereoselective Synthesis of Planar Chiral Phosphoramidites with a Ferrocenophane Scaffold,Organometallics

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Diastereoselective Synthesis of Planar Chiral Phosphoramidites with a Ferrocenophane Scaffold
Organometallics ( IF 2.5 ) Pub Date : 2017-11-15 00:00:00 , DOI: 10.1021/acs.organomet.7b00700
Mathilde Neel ₁ , Pascal Retailleau ₁ , Arnaud Voituriez ₁ , Angela Marinetti ₁

Affiliation

A new family of planar chiral phosphoramidites with a [3]ferrocenophane structure was synthesized. The synthetic strategy involved diastereoselective formation of the chiral ferrocene units from suitable substituted bis-cyclopentadienyl derivatives. Preliminary coordination studies of these ligands were undertaken with the synthesis of palladium and platinum complexes.

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