Synthesis of Chiral Tritylpyrrolidine Derivatives and Their Application to Asymmetric Benzoyloxylation,The Journal of Organic Chemistry

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Synthesis of Chiral Tritylpyrrolidine Derivatives and Their Application to Asymmetric Benzoyloxylation
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2017-11-13 00:00:00 , DOI: 10.1021/acs.joc.7b02562
Mio Shimogaki ₁ , Hiroki Maruyama ₁ , Shingo Tsuji ₁ , Chihiro Homma ₁ , Taichi Kano ₁ , Keiji Maruoka ₁

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An efficient synthesis of novel chiral tritylpyrrolidine derivatives has been developed. Single stereoisomers of various tritylpyrrolidine derivatives can be readily obtained through diastereomer separation by simple silica gel column chromatography. Representative compounds of this class have been shown to be efficient amine organocatalysts for asymmetric benzoyloxylation.

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