Catalytic Asymmetric Intermolecular Allylic Functionalization of Unactivated Internal Alkenes,ACS Catalysis

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Catalytic Asymmetric Intermolecular Allylic Functionalization of Unactivated Internal Alkenes
ACS Catalysis ( IF 11.3 ) Pub Date : 2017-11-15 00:00:00 , DOI: 10.1021/acscatal.7b03081
Liela Bayeh ₁ , Uttam K. Tambar ₁

Affiliation

The asymmetric allylic functionalization of unactivated internal alkenes is an emerging strategy for the conversion of simple unsaturated starting materials into a diverse range of enantioenriched products. This Perspective summarizes the development of reactions wherein a chiral catalyst facilitates the intermolecular stereoselective reaction between an achiral unactivated internal alkene and a reagent.

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