Oxidative P−P Bond Addition to Cobalt(−I): Formation of a Low-Spin Cobalt(III) Phosphanido Complex,Angewandte Chemie International Edition

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Oxidative P−P Bond Addition to Cobalt(−I): Formation of a Low-Spin Cobalt(III) Phosphanido Complex
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-11-15 05:40:47 , DOI: 10.1002/anie.201709140
Peter Coburger ₁ , Serhiy Demeshko ₂ , Christian Rödl ₃ , Evamarie Hey-Hawkins ₁ , Robert Wolf ₃

Affiliation

Cobalt in a P pod: The first homoleptic cobalt phosphanido complex is formed via consecutive oxidative additions of P−P bonds to cobalt(−I). X-ray crystallography and magnetic measurements show that this new cobalt(III) compound is a rare example of a tetrahedral complex with a low-spin ground state.

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