Scandium-Catalyzed Self-Assisted Polar Co-monomer Enchainment in Ethylene Polymerization,Angewandte Chemie International Edition

当前位置： X-MOL 学术 › Angew. Chem. Int. Ed. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Scandium-Catalyzed Self-Assisted Polar Co-monomer Enchainment in Ethylene Polymerization
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-11-15 05:40:27 , DOI: 10.1002/anie.201708797
Jiazhen Chen ₁ , Yanshan Gao ₁ , Binghao Wang ₁ , Tracy L. Lohr ₁ , Tobin J. Marks ₁

Affiliation

Self-assisted: Sc-catalyzed ethylene + amino olefin (AO) copolymerizations proceed with appreciable activity and AO incorporation in the absence of Lewis acid masking agents. Linker-length-dependent AO enchainment patterns and mechanistic probes support an unusual amino-group-assisted enchainment pathway. Binuclear-catalyst-mediated copolymerization rates are less sensitive to AO concentration, and incorporation patterns at large linker lengths implicate bimetallic cooperative enchainment.

中文翻译：

乙烯聚合中dium催化的自助极性共聚单体链

自我辅助：在没有路易斯酸掩蔽剂的情况下，Sc催化的乙烯+氨基烯烃（AO）的共聚反应具有明显的活性，并且AO掺入。取决于接头长度的AO束缚模式和机制探针支持不寻常的氨基辅助束缚途径。双核催化剂介导的共聚速率对AO浓度较不敏感，并且在长连接基团长度处的掺入方式暗示了双金属协作链的形成。

更新日期：2017-11-15

点击分享查看原文

点击收藏

公开下载

阅读更多本刊最新论文本刊介绍/投稿指南11