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Crossover between Tilt Families and Zero Area Thermal Expansion in Hybrid Prussian Blue Analogues
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2017-11-15 05:36:58 , DOI: 10.1002/anie.201708514
Anthony E. Phillips 1 , A. Dominic Fortes 2
Affiliation  

A different tilt: A reassessment of the symmetry of two cyanide-bridged perovskite analogues reveals that phase transitions in these materials arise from competition between two different tilt patterns. Tilt engineering of the hybrid materials provides a way to access combinations of distortions that are rare or impossible among the inorganic perovskites.

中文翻译:

混合普鲁士蓝类似物中倾斜族与零面积热膨胀之间的交叉

不同的倾斜度:对两个氰化物桥接的钙钛矿类似物的对称性的重新评估显示,这些材料中的相变是由两个不同倾斜度图案之间的竞争引起的。杂化材料的倾斜工程设计提供了一种途径来获取无机钙钛矿中罕见或不可能的变形组合。
更新日期:2017-11-15
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