CO2-assisted synthesis of non-symmetric α-diketones directly from aldehydes via C–C bond formation,Green Chemistry

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CO2-assisted synthesis of non-symmetric α-diketones directly from aldehydes via C–C bond formation
Green Chemistry ( IF 9.3 ) Pub Date : 2017-10-04 00:00:00 , DOI: 10.1039/c7gc02425h
Pradipbhai Hirapara _{1,

2,

3,

4} , Daniel Riemer _{1,

2,

3,

4} , Nabanita Hazra _{1,

2,

3,

4} , Jignesh Gajera _{1,

2,

3,

4} , Markus Finger _{1,

2,

3,

4} , Shoubhik Das _{1,

2,

3,

4}

Affiliation

CO₂-assisted various symmetric and non-symmetric α-diketones have been synthesized directly from the corresponding aldehydes using transition metal-free catalysts. This method can even be applied to synthesize pharmaceuticals directly from aldehydes. The crucial role of CO₂ has been investigated in detail and the mechanism is proposed on the basis of experiments and DFT calculations.

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