Bio-based amines through sustainable heterogeneous catalysis,Green Chemistry

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Bio-based amines through sustainable heterogeneous catalysis
Green Chemistry ( IF 9.3 ) Pub Date : 2017-09-18 00:00:00 , DOI: 10.1039/c7gc02299a
M. Pelckmans _{1,

2,

3,

4} , T. Renders _{1,

2,

3,

4} , S. Van de Vyver _{1,

2,

3,

4} , B. F. Sels _{1,

2,

3,

4}

Affiliation

The production of amines from biomass is a growing field of interest. Particularly the amination of bio-based alcohols receives a lot of attention. In this review, we discuss recent progress in the development of efficient heterogeneous catalysts. The substrate scope for the production of bio-based amines is not limited to (hemi)cellulosic alcohols. Other platform chemicals that originate from different biomass fractions, such as lignin, oils, chitin and protein, are also suitable feedstock for the production of amines. This comprehensive review first provides an overview of the available bio-based feedstock candidates. The following section is devoted to the sustainable reaction routes that are available to carry out the desired amination reactions. Next, state-of-the-art technologies are summarized for each substrate class, focussing on heterogeneous catalysis. Special attention is dedicated to the sustainability of the discussed reaction routes. Finally, a critical discussion is provided, together with current challenges and future perspectives regarding the industrial production of bio-based amine chemicals.

中文翻译：

通过可持续的多相催化生物胺

由生物质生产胺是一个日益增长的关注领域。尤其是基于生物的醇的胺化受到很多关注。在这篇综述中，我们讨论了高效多相催化剂开发的最新进展。用于生产生物基胺的底物范围不限于（半）纤维素醇。来自不同生物质部分的其他平台化学品，例如木质素，油，几丁质和蛋白质，也是生产胺类的合适原料。这份全面的综述首先提供了可用的生物基原料候选产品的概述。以下部分专门介绍可用于执行所需胺化反应的可持续反应路线。接下来，总结了每种基材类别的最新技术，着重于非均相催化。特别注意讨论的反应路线的可持续性。最后，提供了重要的讨论，以及有关生物胺类化学品工业生产的当前挑战和未来观点。

更新日期：2017-11-13

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