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Visible-light photooxygenation of α-terpinene in a falling film microreactor
Catalysis Today ( IF 5.3 ) Pub Date : 2017-11-11 , DOI: 10.1016/j.cattod.2017.11.009
Oksana Shvydkiv , Klaus Jähnisch , Norbert Steinfeldt , Alexander Yavorskyy , Michael Oelgemöller

The photooxygenation of α-terpinene was investigated in a falling film microreactor. The formation of microfilms and the flow operation allowed for a safe and controllable production of the bioactive endoperoxide ascaridole. Stepwise investigation of the process parameters resulted in the selective formation of ascaridole of up to 89% and a productivity of 2.5–3.2 mol L−1 h−1, respectively.



中文翻译:

降膜微反应器中α-萜品烯的可见光光氧化

在降膜微反应器中研究了α-萜品烯的光氧化作用。缩微膜的形成和流动操作使得可以安全且可控地生产生物活性内过氧化物a啶。对工艺参数的逐步研究导致选择性地形成了高达89%的a啶,产率分别为2.5–3.2 mol L -1  h -1

更新日期:2017-11-11
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