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Nanoarchitecturing of open metal site Cr-MOFs for oxodiperoxo molybdenum complexes [MoO(O2)2@En/MIL-100(Cr)] as promising and bifunctional catalyst for selective thioether oxidation
Molecular Catalysis ( IF 3.9 ) Pub Date : 2017-11-10 , DOI: 10.1016/j.mcat.2017.11.003
Sadegh Rostamnia , Farahnaz Mohsenzad

In this work, open metal site metal-organic framework of MIL-100(Cr) was selected as a support for the multi-step grafting of molybdenum complexes. The oxodiperoxo molybdenum complexes were coordinated onto the ethylene diamine-decorated MIL-100(Cr) pore cage, that this bifunctional MoO(O2)2@En/MIL-100(Cr) catalyst was successfully applied for H2O2 (30%) mediate green and selective thioether oxidation process. Component activity and recyclability test for the MoO(O2)2@En/MIL-100(Cr) catalyst showed a successful reusability for 8 runs.



中文翻译:

氧二过氧钼配合物[MoO(O 22 @ En / MIL-100(Cr)]的开放金属位点Cr-MOF的纳米结构作为选择性硫醚氧化的有前途和双功能催化剂

在这项工作中,MIL-100(Cr)的开放金属现场金属有机骨架被选作钼络合物多步接枝的载体。将氧二过氧钼配合物配位到乙二胺修饰的MIL-100(Cr)孔笼上,证明该双功能MoO(O 22 @ En / MIL-100(Cr)催化剂已成功用于H 2 O 2(30 %)介导绿色和选择性的硫醚氧化过程。MoO(O 22 @ En / MIL-100(Cr)催化剂的组分活性和可回收性测试显示成功运行了8次。

更新日期:2017-11-10
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