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Nanoarchitecturing of open metal site Cr-MOFs for oxodiperoxo molybdenum complexes [MoO(O2)2@En/MIL-100(Cr)] as promising and bifunctional catalyst for selective thioether oxidation
Molecular Catalysis ( IF 3.9 ) Pub Date : 2017-11-10 , DOI: 10.1016/j.mcat.2017.11.003 Sadegh Rostamnia , Farahnaz Mohsenzad
中文翻译：
氧二过氧钼配合物[MoO（O 2）2 @ En / MIL-100（Cr）]的开放金属位点Cr-MOF的纳米结构作为选择性硫醚氧化的有前途和双功能催化剂
更新日期：2017-11-10
Molecular Catalysis ( IF 3.9 ) Pub Date : 2017-11-10 , DOI: 10.1016/j.mcat.2017.11.003 Sadegh Rostamnia , Farahnaz Mohsenzad
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In this work, open metal site metal-organic framework of MIL-100(Cr) was selected as a support for the multi-step grafting of molybdenum complexes. The oxodiperoxo molybdenum complexes were coordinated onto the ethylene diamine-decorated MIL-100(Cr) pore cage, that this bifunctional MoO(O2)2@En/MIL-100(Cr) catalyst was successfully applied for H2O2 (30%) mediate green and selective thioether oxidation process. Component activity and recyclability test for the MoO(O2)2@En/MIL-100(Cr) catalyst showed a successful reusability for 8 runs.
中文翻译：
氧二过氧钼配合物[MoO（O 2）2 @ En / MIL-100（Cr）]的开放金属位点Cr-MOF的纳米结构作为选择性硫醚氧化的有前途和双功能催化剂
在这项工作中，MIL-100（Cr）的开放金属现场金属有机骨架被选作钼络合物多步接枝的载体。将氧二过氧钼配合物配位到乙二胺修饰的MIL-100（Cr）孔笼上，证明该双功能MoO（O 2）2 @ En / MIL-100（Cr）催化剂已成功用于H 2 O 2（30 ％）介导绿色和选择性的硫醚氧化过程。MoO（O 2）2 @ En / MIL-100（Cr）催化剂的组分活性和可回收性测试显示成功运行了8次。
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