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Oxidation behavior of ZrB2-SiC-ZrC in oxygen-hydrogen torch environment
Journal of the European Ceramic Society ( IF 5.8 ) Pub Date : 2017-11-11 , DOI: 10.1016/j.jeurceramsoc.2017.11.024
Yuki Kubota , Mamoru Yano , Ryo Inoue , Yasuo Kogo , Ken Goto

The oxidation behavior of four ZrB2-SiC-ZrC compositions with varying ZrC contents (20, 34, 50, and 64 vol.%) was compared to that of ZrB2-SiC. The ceramics were oxidized at 1700 °C in an oxygen-hydrogen torch environment. The liquid oxide on the ZrB2-SiC sample came off from the surface under such an environment. In contrast, the all ZrB2-SiC-ZrC samples maintained the convex oxide on the surface, which consisted of ZrO2 and SiO2. The convex oxide of ZSZ with higher ZrC content was thicker, with the exception of ZrB2-SiC-64vol.%ZrC sample. The ZrB2-SiC-64vol.%ZrC sample formed a ZrO2-rich layer, which was clearly denser than the ZrO2-SiO2. This densification was caused by ZrO2-sintering, and it was specific behavior under the dynamic pressure.



中文翻译:

ZrB 2 -SiC-ZrC在氢氧炬环境中的氧化行为

四个的ZrB氧化行为2 -SiC-的ZrC组合物具有不同的ZrC内容(20,34,50,和64体积%)中的溶液相比的ZrB的2 -SiC。在氧气-氢气炬环境中,将陶瓷在1700°C的温度下氧化。在这种环境下,ZrB 2 -SiC样品上的液态氧化物从表面脱落。相反,所有ZrB 2 -SiC-ZrC样品均在表面上保留了由ZrO 2和SiO 2组成的凸形氧化物。ZrC含量较高的ZSZ凸氧化物较厚,但ZrB 2 -SiC-64vol。%ZrC样品除外。ZrB 2 -SiC-64vol。%ZrC样品形成ZrO 2层,显然比ZrO 2 -SiO 2致密。该致密化是由ZrO 2烧结引起的,并且是在动态压力下的特定行为。

更新日期:2017-11-11
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