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Friedel–Crafts Alkylation of Aromatics by TiCl4-Promoted Ring Cleavage of 3-Arylcyclobutanones
Synthesis ( IF 2.2 ) Pub Date : 2017-11-06 , DOI: 10.1055/s-0036-1591497
Jun-ichi Matsuo , Mayu Kanie , Tomoyuki Yoshimura

Dedicated to Professor Teruaki Mukaiyama in celebration of his 90th birthday

Abstract

Ring cleavage of 3-arylcyclobutanones and successive Friedel–Crafts alkylation of methoxy- or alkyl-substituted benzene derivatives proceeded to give 3,3-diarylbutan-2-ones by activation with titanium tetrachloride.

Ring cleavage of 3-arylcyclobutanones and successive Friedel–Crafts alkylation of methoxy- or alkyl-substituted benzene derivatives proceeded to give 3,3-diarylbutan-2-ones by activation with titanium tetrachloride.



中文翻译:

TiCl4促进的3-芳基环丁酮环裂解的Friedel-Crafts芳烃烷基化

致力于向山辉明教授在他90的庆祝生日

抽象的

3-芳基环丁酮的环裂解和甲氧基或烷基取代的苯衍生物的连续Friedel-Crafts烷基化通过四氯化钛活化而得到3,3-二芳基丁烷-2-酮。

3-芳基环丁酮的环裂解和甲氧基或烷基取代的苯衍生物的连续Friedel-Crafts烷基化通过四氯化钛活化而得到3,3-二芳基丁烷-2-酮。

更新日期:2017-11-06
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