Abstract

The treatment of 9,10-diphenylanthracenes with DDQ in the presence of TfOH readily gave the corresponding rubicene derivatives in good yields. The effects of oxidant, acid, substituent, and other conditions are discussed. This protocol involving the Scholl reaction is convenient for the preparation of some rubicene derivatives from conventional starting materials.

The treatment of 9,10-diphenylanthracenes with DDQ in the presence of TfOH readily gave the corresponding rubicene derivatives in good yields. The effects of oxidant, acid, substituent, and other conditions are discussed. This protocol involving the Scholl reaction is convenient for the preparation of some rubicene derivatives from conventional starting materials.

中文翻译：

---

通过Scholl反应轻松合成卢比汀

摘要

在TfOH存在下用DDQ处理9,10-二苯基蒽很容易以高收率得到相应的红宝石衍生物。讨论了氧化剂，酸，取代基和其他条件的影响。该涉及Scholl反应的方案对于由常规起始原料制备某些红宝石衍生物是方便的。

在TfOH存在下用DDQ处理9,10-二苯基蒽很容易以高收率得到相应的红宝石衍生物。讨论了氧化剂，酸，取代基和其他条件的影响。该涉及Scholl反应的方案对于由常规起始原料制备某些红宝石衍生物是方便的。