Synthesis ( IF 2.2 ) Pub Date : 2017-08-30 , DOI: 10.1055/s-0036-1589101 Paul Knochel 1 , Andreas Benischke 1 , Alexandre Desaintjean 2 , Thomas Juli 1 , Gérard Cahiez 2
Abstract
A catalytic system consisting of Ni(acac)2 (5 mol%) and 4-fluorostyrene (20 mol%) allows a convenient cross-coupling of functionalized organomanganese reagents with a variety of aryl and heteroaryl halides leading to polyfunctionalized diaryl- and arylheteroarylmethane derivatives.
A catalytic system consisting of Ni(acac)2 (5 mol%) and 4-fluorostyrene (20 mol%) allows a convenient cross-coupling of functionalized organomanganese reagents with a variety of aryl and heteroaryl halides leading to polyfunctionalized diaryl- and arylheteroarylmethane derivatives.
中文翻译:
镍催化的功能化有机锰试剂与4-氟苯乙烯促进的芳基和杂芳基卤化物的交叉偶联
摘要
由Ni(acac)2(5 mol%)和4-氟苯乙烯(20 mol%)组成的催化系统可以方便地将官能化的有机锰试剂与各种芳基和杂芳基卤化物交叉偶联,从而得到多官能化的二芳基和芳基杂芳基甲烷衍生物。
由Ni(acac)2(5 mol%)和4-氟苯乙烯(20 mol%)组成的催化系统可以方便地将官能化的有机锰试剂与各种芳基和杂芳基卤化物交叉偶联,从而得到多官能化的二芳基和芳基杂芳基甲烷衍生物。