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Shifting Lu2SiO5 crystal to eutectic structure by laser floating zone
Journal of the European Ceramic Society ( IF 5.8 ) Pub Date : 2017-11-04 , DOI: 10.1016/j.jeurceramsoc.2017.11.003
F. Rey-García , N. Ben Sedrine , A.J.S. Fernandes , T. Monteiro , F.M. Costa

Starting from stoichiometric mixtures of lutetium and silicon oxides, Lu2SiO5 (LSO) crystals to eutectic ceramic rods were obtained using the laser floating zone (LFZ) technique in air at growth rates ranging from 200 to 5 mm/h. The newly obtained eutectic is formed by Lu2O3 fibrils and/or lamellae into a LSO matrix being its formation induced by a SiO2 evaporation process during the LFZ growth.

Scanning electron microscopy (SEM) and Raman spectroscopy studies allowed observing how growth rate affects microstructural evolution, namely the transition from single crystal to eutectic. SEM observations show that the eutectics present alternated monophasic oxyorthosilicate regions with biphasic Lu2SiO5/Lu2O3 ones identified by X-Ray diffraction as C2/c monoclinic Lu2SiO5 and Ia3¯ cubic lutetium oxide.

While the luminescence phenomena were found to be only dependent on the excitation energy, a pronounced UV light-induced reversible photochromic effect was observed in the samples grown at slower rates.



中文翻译:

通过激光浮区将Lu 2 SiO 5晶体转变为共晶结构

从of和氧化硅的化学计量混合物开始,使用激光浮区(LFZ)技术在空气中以200至5 mm / h的生长速率获得Lu 2 SiO 5(LSO)晶体至共晶陶瓷棒。新获得的共晶是由Lu 2 O 3的原纤维和/或薄片形成的LSO基体,是在LFZ生长期间由SiO 2蒸发过程诱导形成的。

扫描电子显微镜(SEM)和拉曼光谱研究允许观察生长速率如何影响微观结构的演变,即从单晶到共晶的转变。SEM观察表明,共晶存在交替的单相含正硅酸盐的单相区域,双相Lu 2 SiO 5 / Lu 2 O 3通过X射线衍射鉴定为C2 / c单斜度Lu 2 SiO 5和Ia3¯ 立方氧化oxide。

虽然发现发光现象仅取决于激发能量,但是在以较低速率生长的样品中观察到明显的紫外线诱导的可逆光致变色效应。

更新日期:2017-11-10
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