Direct ratiometric detection of nitric oxide with Cu(II)-based fluorescent probes,Journal of Materials Chemistry B

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Direct ratiometric detection of nitric oxide with Cu(II)-based fluorescent probes
Journal of Materials Chemistry B ( IF 6.1 ) Pub Date : 2017-10-26 00:00:00 , DOI: 10.1039/c7tb02666h
A. Loas _{1,

2,

3,

4} , S. J. Lippard _{1,

2,

3,

4}

Affiliation

We report the first Cu(II)-based fluorescent sensors for ratiometric detection of nitric oxide. The two probes operate by energy transfer between hydroxycoumarin and fluorescein chromophores, contain polyproline or piperazine as rigid spacers, and elicit a rapid and selective ratiometric response upon direct reaction with nitric oxide.

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