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Selective S-Deacetylation of Functionalized Thioacetates Catalyzed by Dy(OTf)3
Asian Journal of Organic Chemistry ( IF 2.7 ) Pub Date : 2017-11-09 12:40:28 , DOI: 10.1002/ajoc.201700481
Jiun-Rung Guo,Hsin-Yi Huang,Yi-Ling Yan,Chien-Fu Liang

Dy another day: A Dy(OTf)3-catalyzed S-deacetylation of functionalized thioesters has been developed. Moreover, selective S-deacetylation can be achieved by combining Dy(OTf)3 with NaHCO3. Furthermore, glycosyl 1-thioacetate has been successfully transformed into glycosyl 1-thiol by using Dy(OTf)3 in a co-solvent system.

中文翻译:

Dy(OTf)3催化官能化硫代乙酸酯的选择性S-脱乙酰化

另一天的Dy:已经开发了Dy(OTf)3催化的官能化硫酯的S-脱乙酰化。而且,可以通过将Dy(OTf)3与NaHCO 3结合来实现选择性的S-脱乙酰化。此外,通过在共溶剂系统中使用Dy(OTf)3,已成功地将糖基1-硫代乙酸酯转化为糖基1-硫醇。
更新日期:2017-11-09
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