Palladium‐catalysed O‐Allylation of α‐Hydroxyphosphonates: An Expedient Entry into Phosphono‐oxaheterocycles,Advanced Synthesis & Catalysis

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Palladium‐catalysed O‐Allylation of α‐Hydroxyphosphonates: An Expedient Entry into Phosphono‐oxaheterocycles
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2017-11-28 , DOI: 10.1002/adsc.201701150
Mansour Dolé Kerim ₁ , Martin Cattoen ₂ , Nicolas Fincias _{1,

2} , Aurélie Dos Santos ₁ , Stellios Arseniyadis ₂ , Laurent El Kaïm ₁

Affiliation

We report here an unprecedented palladium‐catalysed O‐allylation of α‐hydroxyphosphonates. The method was eventually included in a sequential Pudovik/Tsuji‐Trost type O‐allylation/Ring‐Closing Metathesis to afford a variety of phosphorylated heterocycles of various sizes ranging from 5 to 16 starting from readily available aldehydes.

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