Highly diastereoselective access to polyfunctionalized 1,3-oxazines promoted by Brønsted/Lewis acids,Organic Chemistry Frontiers

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Highly diastereoselective access to polyfunctionalized 1,3-oxazines promoted by Brønsted/Lewis acids
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2017-10-26 00:00:00 , DOI: 10.1039/c7qo00891k
Clovis Peter _{1,

2,

3,

4,

5} , Philippe Geoffroy _{1,

2,

3,

4,

5} , Michel Miesch _{1,

2,

3,

4,

5}

Affiliation

The Brønsted/Lewis acid catalyzed reaction of pyrrolidone, piperidone and isoindolinone derivatives tethered to α,β-unsaturated ketones or aldehydes afforded exclusively polyfunctionalized 1,3-oxazines with high diastereoselectivities and in high yields.

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