当前位置: X-MOL 学术Macromolecules › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
50th Anniversary Perspective: Solid-State Multistimuli, Multiresponsive Polymeric Materials
Macromolecules ( IF 5.1 ) Pub Date : 2017-11-02 00:00:00 , DOI: 10.1021/acs.macromol.7b01607
Katie M. Herbert , Stephen Schrettl 1 , Stuart J. Rowan 2 , Christoph Weder 1
Affiliation  

The field of stimuli-responsive polymers has grown in the past three decades from a few obscure examples to one of the most vibrant domains of modern macromolecular science. Indeed, the research, development, and implementation of tailored materials that can respond in predefined ways to specific stimuli now cut across most areas in which “traditional” polymers play a role, and an ever-growing range of commercial products benefits from this class of materials. This Perspective is devoted to multistimuli, multiresponsive (MSMR) polymers, which are those materials that are able to respond to multiple, different stimuli with multiple, distinct responses. Somewhat akin to living systems, which have evolved to adapt and respond in complex ways to (combinations of) different environmental cues, MSMR polymers can offer a broad range of complex properties and functions. While much of the work on MSMR polymers has been devoted to the investigation of solutions or gels, this Perspective concentrates on solid materials, as this is the state of matter in which the vast majority of polymers are currently employed. In a tutorial fashion, an outline of some of the most common mechanisms used to implement stimuli-responsive behavior in polymer solids is provided. To convey a glimpse of the potential and the challenges of these general design principles, select examples of materials that display multistimuli, single-response as well as single-stimulus multiresponse behavior are presented, before polymeric materials that are truly multistimuli, multiresponsive are discussed, and an outlook on possible directions that future work in the field may take is presented.

中文翻译:

五十周年纪念:固态多刺激,多响应聚合物材料

在过去的三十年中,刺激响应性聚合物的领域已经从几个不起眼的例子发展成为现代大分子科学中最活跃的领域之一。实际上,可以以预定方式对特定刺激做出反应的量身定制的材料的研究,开发和实施,如今已遍及“传统”聚合物发挥作用的大多数领域,并且此类产品的种类越来越多,商业产品也从中受益。材料。本“透视图”致力于多刺激,多反应(MSMR)聚合物,这些聚合物能够对多种不同的刺激做出多种不同的反应。与生命系统有些相似,它们已经进化为以复杂的方式适应并响应不同的环境提示(并结合在一起),MSMR聚合物可以提供广泛的复杂特性和功能。尽管有关MSMR聚合物的许多工作都致力于溶液或凝胶的研究,但本“观点”着重于固体材料,因为这是目前使用绝大多数聚合物的物质状态。以教程的方式,概述了用于在聚合物固体中实现刺激响应行为的一些最常见的机制。为了传达这些一般设计原理的潜力和挑战,在讨论真正具有多重刺激,多反应性的聚合物材料之前,先介绍一些显示多重刺激,单响应以及单一刺激多重响应行为的材料示例,
更新日期:2017-11-02
down
wechat
bug