Synthesis and Catalytic Benefits of Tetranuclear Gold(I) Complexes with a C4-Symmetric Tetratriazol-5-ylidene,Organometallics

当前位置： X-MOL 学术 › Organometallics › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Synthesis and Catalytic Benefits of Tetranuclear Gold(I) Complexes with a C4-Symmetric Tetratriazol-5-ylidene
Organometallics ( IF 2.5 ) Pub Date : 2017-11-01 00:00:00 , DOI: 10.1021/acs.organomet.7b00712
Mariana Flores-Jarillo ₁ , Daniel Mendoza-Espinosa ₂ , Verónica Salazar-Pereda ₁ , Simplicio González-Montiel ₁

Affiliation

The facile preparation of a C₄-symmteric tetratriazolium salt and its subsequent metalation to generate a series of tetranuclear mesoionic carbene gold(I) complexes is presented. The complete structural characterization of the metallic carbenes and the benefits of cooperative catalysis in the processes of hydroamination and hydrohydrazination of terminal alkynes are discussed.

中文翻译：