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Cp*RhIII-Catalyzed C–H Amidation of Ferrocenes
Organometallics ( IF 2.8 ) Pub Date : 2017-11-01 00:00:00 , DOI: 10.1021/acs.organomet.7b00691
Shao-Bo Wang 1 , Qing Gu 2 , Shu-Li You 1, 2
Affiliation  

Amidation of N-containing heteroaryl ferrocenes with 1,4,2-dioxazol-5-ones as the amidated reagents was achieved via a Rh-catalyzed direct C–H functionalization reaction. Under mild reaction conditions, a wide range of N-ferrocenyl amides were obtained in up to 99% yield. Transformations of the amide group were also feasible.

中文翻译:

Cp * Rh III-二茂铁催化的CHH酰胺化

含氮杂芳基二茂铁与1,4,2-二恶唑-5-酮作为酰胺化试剂的酰胺化是通过Rh催化的直接C–H官能化反应实现的。在温和的反应条件下,以高达99%的收率获得了多种N-二茂铁酰胺。酰胺基的转化也是可行的。
更新日期:2017-11-01
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