Investigating the Structure and Reactivity of Azolyl-Based Copper(I)–NHC Complexes: The Role of the Anionic Ligand,ACS Catalysis

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Investigating the Structure and Reactivity of Azolyl-Based Copper(I)–NHC Complexes: The Role of the Anionic Ligand
ACS Catalysis ( IF 11.3 ) Pub Date : 2017-11-01 00:00:00 , DOI: 10.1021/acscatal.7b02737
Michael Trose ₁ , Fady Nahra ₂ , Albert Poater _{3,

4} , David B. Cordes ₁ , Alexandra M. Z. Slawin ₁ , Luigi Cavallo ₃ , Catherine S. J. Cazin _{1,

2}

Affiliation

A family of copper(I)–NHC azolyl complexes was synthesized and deployed in the hydrosilylation of dicyclo-hexylketone to probe the role of the anionic ligand on catalytic performance. The azolyl ligand is shown to have a crucial role in catalytic activity without the need for additives, and this at very low catalyst loading.

中文翻译：

研究基于氮唑基的铜（I）-NHC配合物的结构和反应性：阴离子配体的作用

合成了铜（I）-NHC偶氮基铜配合物家族，并将其部署在二环己基酮的硅氢加成反应中，以研究阴离子配体对催化性能的作用。偶氮基配体在不需要添加剂的情况下在催化活性中起着至关重要的作用，并且在非常低的催化剂载量下就可以发挥重要作用。

更新日期：2017-11-01

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