Cationic Vacancy Defects in Iron Phosphide: A Promising Route toward Efficient and Stable Hydrogen Evolution by Electrochemical Water Splitting,ChemSusChem

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Cationic Vacancy Defects in Iron Phosphide: A Promising Route toward Efficient and Stable Hydrogen Evolution by Electrochemical Water Splitting
ChemSusChem ( IF 7.5 ) Pub Date : 2017-10-27 02:21:24 , DOI: 10.1002/cssc.201701565
Wai Ling Kwong _{1,

2} , Eduardo Gracia-Espino ₃ , Cheng Choo Lee ₄ , Robin Sandström ₃ , Thomas Wågberg ₃ , Johannes Messinger _{1,

2}

Affiliation

When less is more: Fe-vacancy-rich FeP, prepared by chemical leaching of Mg that is introduced into FeP as sacrificial dopant, exhibits superior electrocatalytic activity for hydrogen evolution reaction compared to pristine FeP and Mg-doped FeP. The presence of cationic vacancy defects modulates the structural and electronic structures of FeP, thereby resulting in enhanced proton trapping and surface interaction with adsorbed hydrogen atoms.

中文翻译：

磷化铁中的阳离子空位缺陷：通向电化学水分解的高效稳定氢释放的有前途的途径

少则多：富Fe空位的FeP是通过化学浸出作为牺牲性掺杂剂引入到FeP中的Mg制备的，与原始FeP和Mg掺杂的FeP相比，它对氢的析出反应具有优异的电催化活性。阳离子空位缺陷的存在调节FeP的结构和电子结构，从而导致质子捕获增强，并与吸附的氢原子发生表面相互作用。

更新日期：2017-10-27

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