Copper-catalysed dehydrogenative α-C(sp3)–H amination of tetrahydroquinolines with O-benzoyl hydroxylamines,Organic Chemistry Frontiers

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Copper-catalysed dehydrogenative α-C(sp3)–H amination of tetrahydroquinolines with O-benzoyl hydroxylamines
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2017-10-12 00:00:00 , DOI: 10.1039/c7qo00794a
He Zhao _{1,

2,

3,

4,

5} , Xiuwen Chen _{1,

2,

3,

4,

5} , Huanfeng Jiang _{1,

2,

3,

4,

5} , Min Zhang _{1,

2,

3,

4,

5}

Affiliation

A copper-catalysed dehydrogenative α-C(sp³)–H amination of tetrahydroquinolines with O-benzoyl hydroxylamines has been demonstrated for the first time, which proceeds with the merits of operational simplicity, good functional tolerance, mild conditions, the use of O₂ as the oxidant and no need for the installation of directing groups.

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