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Pd-Catalyzed Cyclopropanation Reaction of Aliphatic Ketones with Monosubstituted Allyl Reagents
Asian Journal of Organic Chemistry ( IF 2.7 ) Pub Date : 2017-10-24 02:01:49 , DOI: 10.1002/ajoc.201700541
Jian-Qiang Huang 1 , Jing-Feng Zhao 2 , Zhen Yang 1 , Chang-Hua Ding 1 , Xue-Long Hou 1, 3 , Xiao-Shui Peng 4 , Henry Nai Ching Wong 3, 4
Affiliation  

Selected cyclopropanes: A Pd-catalyzed cyclopropanation reaction with aliphatic ketones as nucleophiles using a modified pyridine-NHC ligand was achieved. The reaction afforded the corresponding cyclopropanes in moderate to good yields with high cyclopropane/allylation selectivity.

中文翻译:

Pd催化的脂肪族酮与单取代的烯丙基试剂的环丙烷化反应

选择的环丙烷:使用修饰的吡啶-NHC配体,实现了以脂肪族酮为亲核体的Pd催化的环丙烷化反应。该反应以中等至良好的产率提供了具有高环丙烷/烯丙基化选择性的相应环丙烷。
更新日期:2017-10-24
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