B2(OH)4-mediated one-pot synthesis of tetrahydroquinoxalines from 2-amino(nitro)anilines and 1,2-dicarbonyl compounds in water,Organic Chemistry Frontiers

当前位置： X-MOL 学术 › Org. Chem. Front. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

B2(OH)4-mediated one-pot synthesis of tetrahydroquinoxalines from 2-amino(nitro)anilines and 1,2-dicarbonyl compounds in water
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2017-08-09 00:00:00 , DOI: 10.1039/c7qo00604g
Sensheng Liu _{1,

2,

3,

4,

5} , Yanmei Zhou _{1,

2,

3,

4,

5} , Yuebo Sui _{1,

2,

3,

4,

5} , Huan Liu _{1,

2,

3,

4,

5} , Haifeng Zhou _{1,

2,

3,

4,

5}

Affiliation

A practical one-pot synthesis of tetrahydroquinoxalines from readily available 2-amino(nitro)anilines and 1,2-dicarbonyl compounds mediated by diboronic acid with water as both a solvent and a hydrogen donor under metal-free conditions has been discovered. The deuterium labeling experiments with D₂O were also performed to demonstrate that water acts as the hydrogen donor.

中文翻译：

B ₂（OH）₄介导的2-氨基（硝基）苯胺和1,2-二羰基化合物在水中一锅合成四氢喹喔啉

已经发现了在无金属条件下由二硼酸介导的以水为溶剂和氢供体的，由容易获得的2-氨基（硝基）苯胺和1,2-二羰基化合物介导的一锅合成四氢喹喔啉的实用方法。还用D ₂ O进行了氘标记实验，以证明水充当氢供体。

更新日期：2017-10-25

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11