Oxidative Coupling of â-O-4′ Dilignol Models Leading to Polycyclic Products with Rare Interlignol Linkages,Asian Journal of Organic Chemistry

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Oxidative Coupling of â-O-4′ Dilignol Models Leading to Polycyclic Products with Rare Interlignol Linkages
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2017-10-24 11:35:26 , DOI: 10.1002/ajoc.201700529
Chang Peng _{1,

2} , Wujun Liu _{1,

3} , Siyang Ning ₁ , Guangbo Ge ₁ , Zongbao K. Zhao _{1,

3,

4}

Affiliation

Polycycles containing rare interlignol linkages were obtained from β-O-4′ type dilignols via oxidative coupling reactions. Oxidative coupling of these dilignols with hypervalent iodine(III) reagents led to two series of highly fused polycyclic products, dibenzo[b,d]oxepine and 2,7-dioxabicyclo[3,3,1]nonane derivatives.

中文翻译：

â-O-4′Dilignol模型的氧化偶联导致具有稀少的Interlignol链接的多环产物

通过氧化偶合反应从β- O -4 '型二木酚中得到含有稀少的木酚间键的多环。这些二木酚与高价碘（III）试剂的氧化偶联导致了两个高度稠合的多环产物，即二苯并[ b，d ]氧杂环丁烷和2,7-二氧杂双环[3,3,1]壬烷衍生物。

更新日期：2017-10-25

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