The hydrosilylation reaction of diphenylsilane and phthalaldehyde is catalyzed by heteroscorpionate zinc hydride complex LZnH (1, L = (^MePz)₂CP(Ph)₂NPh, ^MePz = 3,5‐dimethylpyrazolyl). Both terephthalaldehyde (tPAA) and isophthalaldehyde (iPAA) affords linear polymer; however, when PAA is used, a seven‐membered cyclic silyl ether is formed. These products are characterized by ¹H and ¹³C NMR spectra. Other properties of polymers are determined by gel permeation chromatography (GPC)–multiangle laser‐light scattering, differential scanning calorimetry, and thermogravimetry.

中文翻译：

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锌催化的芳族二醛与二苯基硅烷的氢化硅烷化共聚合

异蝎子氢化锌配合物LZnH（1，L =（^Me Pz）₂ CP（Ph）₂ NPh，^Me Pz = 3,5-二甲基吡唑基）催化二苯甲硅烷与苯甲醛的硅氢加成反应。对苯二甲醛（t PAA）和间苯二甲醛（i PAA）均可提供线性聚合物；但是，当使用PAA时，会形成七元环甲硅烷基醚。这些产物的特征在于¹ H和¹³ C NMR光谱。聚合物的其他性能通过凝胶渗透色谱（GPC）–多角度激光散射，差示扫描量热法和热重法测定。