Conjugated Microporous Polymers for Heterogeneous Catalysis,Chemistry - An Asian Journal

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Conjugated Microporous Polymers for Heterogeneous Catalysis
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2017-12-07 , DOI: 10.1002/asia.201701107
Yun-Bing Zhou ₁ , Zhuang-Ping Zhan ₁

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Conjugated microporous polymers (CMPs) are a class of crosslinked polymers that combine permanent micropores with π‐conjugated skeletons and possess three‐dimensional (3D) networks. Compared with conventional materials such as metal–organic frameworks (MOFs) and covalent organic frameworks (COFs), CMPs usually have superior chemical and thermal stability. CMPs have made significant progress in heterogeneous catalysis in the past seven years. With a bottom‐up strategy, catalytic moieties can be directly introduced into in the framework to produce heterogeneous CMP catalysts. Higher activity, stability, and selectivity can be obtained with heterogeneous CMP catalysts in comparison with their homogeneous analogs. In addition, CMP catalysts can be easily isolated and recycled. In this review, we focus on CMPs as an intriguing platform for developing various highly efficient and recyclable heterogeneous catalysts in organic reactions. The design, synthesis, and structure of these CMP catalysts are also discussed in this focus review.

中文翻译：

用于非均相催化的共轭微孔聚合物

共轭微孔聚合物（CMP）是一类交联聚合物，将永久性微孔与π共轭骨架结合在一起，并具有三维（3D）网络。与金属-有机骨架（MOF）和共价有机骨架（COF）等常规材料相比，CMP通常具有优异的化学和热稳定性。在过去的七年中，CMP在非均相催化方面取得了重大进展。通过自下而上的策略，可以将催化部分直接引入到框架中以生产多相CMP催化剂。与均相类似物相比，使用多相CMP催化剂可以获得更高的活性，稳定性和选择性。另外，CMP催化剂可以容易地分离和再循环。在这篇评论中，我们将CMP视为吸引人的平台，用于开发有机反应中各种高效且可回收的多相催化剂。这些CMP催化剂的设计，合成和结构也在本重点综述中进行了讨论。

更新日期：2017-12-07

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