Neutral d¹⁰ coinage Metal Organic Chalcogenolates (MOCs) exist as oligomeric species and coordination polymers with the formula [M(ER)]_n, where M = Cu(I), Ag(I), Au(I) and ER = ⁻SR, ⁻SeR, ⁻TeR. They have been known for a long time for their applications in pharmaceuticals, for their structural analogy to metaloproteins and as crucial intermediates in the synthesis of functionalized nanoparticles. These hybrid materials exhibit high potential as tunable compounds in terms of dimensionality of the network and functionality of the organic part to tailor their electronic, conductive and photophysical properties. This review reports the synthesis, structure and properties of the 40 neutral MOCs and 3 anionic monometallic species, [M(ER)₂]⁻. A total of 23 oligomers, 13 1D and 4 2D coordination polymers are described, and presence of weak interactions such as hydrogen bonds and metalophilic interactions are discussed.

中文翻译：

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d ¹⁰造币金属有机硫属元素化物：从低聚物到配位聚合物

中性d ¹⁰造币金属有机硫属元素化物（MOC）以低聚物质和配位聚合物的形式存在，通式为[M（ER）] _n，其中M = Cu（I），Ag（I），Au（I）和ER =  ⁻ SR ，^-丝氨酸，^-TeR。由于它们在药物中的应用，与金属蛋白的结构相似以及作为功能化纳米粒子合成中的关键中间体，它们早已为人所知。这些杂化材料在网络的尺寸和有机部分的功能方面具有很高的潜力，可作为可调化合物来调整其电子，导电和光物理性质。这篇综述报告了40种中性MOC和3种阴离子单金属物种[M（ER）₂ ] ^-的合成，结构和性质。总共描述了23个低聚物，13个1D和4个2D配位聚合物，并讨论了弱相互作用（例如氢键和亲金属相互作用）的存在。