Click and Click‐Inspired Chemistry for the Design of Sequence‐Controlled Polymers,Macromolecular Rapid Communications

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Click and Click‐Inspired Chemistry for the Design of Sequence‐Controlled Polymers
Macromolecular Rapid Communications ( IF 4.2 ) Pub Date : 2017-10-09 , DOI: 10.1002/marc.201700469
Steven Martens ₁ , Joshua O. Holloway ₁ , Filip. E. Du Prez ₁

Affiliation

During the previous decade, many popular chemical reactions used in the area of “click” chemistry and similarly efficient “click‐inspired” reactions have been applied for the design of sequence‐defined and, more generally, sequence‐controlled structures. This combination of topics has already made quite a significant impact on scientific research to date and has enabled the synthesis of highly functionalized and complex oligomeric and polymeric structures, which offer the prospect of many exciting further developments and applications in the near future. This minireview highlights the fruitful combination of these two topics for the preparation of sequence‐controlled oligomeric and macromolecular structures and showcases the vast number of publications in this field within a relatively short span of time. It is divided into three sections according to the click‐(inspired) reaction that has been applied: copper‐catalyzed azide–alkyne cycloaddition, thiol‐X, and related thiolactone‐based reactions, and finally Diels–Alder‐chemistry‐based routes are outlined, respectively.

中文翻译：

单击和单击启发化学用于序列控制聚合物的设计

在过去的十年中，“点击”化学领域中使用了许多流行的化学反应，以及类似的高效“点击激发”反应，已被用于序列定义的，更普遍的是序列控制的结构的设计。迄今为止，这些主题的组合已经对科学研究产生了重大影响，并实现了高度功能化和复杂的低聚物和聚合物结构的合成，这为不久的将来提供了许多令人振奋的进一步发展和应用前景。这篇小型综述着重介绍了这两个主题在序列控制的寡聚和大分子结构的制备上的卓有成效的结合，并展示了在相对较短的时间内该领域的大量出版物。

更新日期：2017-10-09

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