Visible-light-induced sulfonylation/cyclization of vinyl azides: one-pot construction of 6-(sulfonylmethyl)phenanthridines†,Organic Chemistry Frontiers

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Visible-light-induced sulfonylation/cyclization of vinyl azides: one-pot construction of 6-(sulfonylmethyl)phenanthridines†
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2017-10-09 00:00:00 , DOI: 10.1039/c7qo00790f
Liu-Liang Mao _{1,

2,

3,

4,

5} , Da-Gui Zheng _{1,

2,

3,

4,

5} , Xian-Hong Zhu _{1,

2,

3,

4,

5} , An-Xi Zhou _{1,

2,

3,

4,

5} , Shang-Dong Yang _{5,

6,

7,

8}

Affiliation

Visible-light-induced sulfonylation/cyclization of vinyl azides has been developed for the synthesis of 6-(sulfonylmethyl)-phenanthridines. This facile and efficient approach used simple and readily available sulfonyl chlorides as the sulfonylation reagent for the construction of C–S bonds and triggered the formation of the C–N bond with mild conditions, broad substrate scope, and high functional group tolerance.

中文翻译：

可见光诱导的乙烯基叠氮化物的磺酰化/环化：一锅构建6-（磺酰基甲基）菲啶†

已经开发了可见光诱导的乙烯基叠氮化物的磺酰化/环化反应，用于合成6-（磺酰基甲基）-菲啶。这种简便有效的方法使用简单易用的磺酰氯作为磺酰化试剂来构建C–S键，并在温和的条件，较宽的底物范围和较高的官能团耐受性下触发了C–N键的形成。

更新日期：2017-10-09

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